Solid-State Structural Transformations of Two AgI Supramolecular Polymorphs to Another Polymer upon Absorption of HNO3 Vapors

被引：32

作者：

Akhbari, Kamran ^{[1
]}

Morsali, Ali ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 06期

关键词：

COORDINATION POLYMERS; SILVER(I) COMPLEXES; BONDS; CO-III(ETA(5)-C5H4COOH)(ETA(5)-C5H4COO); STACKING; ACIDS;

D O I：

10.1021/ic3008415

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solid-state structural transformation of two polymorphic forms of [Ag(8-HqH)(8-Hq)](n) (1 alpha and 1 beta, where 8-HqH = 8-hydroxyquinoline and 8-Hq(-) = 8-hydroxyquinolate) to {[Ag(8-HqH)(2)]NO3}(n) (2) has been observed upon solid-gas reaction of compounds 1 alpha and 1 beta with HNO3 vapors. Solid-gas reaction of compound 2 with hydrated vapors of NH3 results in the formation of only the 1 beta polymorph, while solid-solid reaction of compound 2 with KOH results in the formation of a la and 1 beta mixture with chiral and achiral space groups of P2(1)2(1)2(1) and Pbcn, respectively.

引用

页码：2787 / 2789

页数：3

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