Surface modified BaTiO3 nanoparticles by titanate coupling agent induce significantly enhanced breakdown strength and larger energy density in PVDF nanocomposite

Dielectric capacitors are promising in micro-electronics, portable equipment and hybrid electric vehicles due to their specific features of flexibility, ultrahigh operating voltage and fast charging-discharging rate. The dielectric properties of polymer-based nanocomposite are much related to the interface binding between fillers and matrix. In this work, a surface modification approach employed newfound titanate coupling agent was developed to improve the compatibility between BT nanoparticles and PVDF matrix. After treated by the modifier TC-2, a coating layer contained with active organic groups was formed on the surface of BT nanoparticles. Benefited from the improved dispersibility and compatibility of modified BT nanoparticles in PVDF matrix, the breakdown strength of the nanocomposites was much enhanced. The monodisperse mBT-2 nanoparticles treated with appropriate amount of modifier dramatically enlarged the breakdown strength from 397 kV/mm for neat PVDF to 517 kV/aim for 4 vol% mBT-2 loading nanocomposite. Compared with BT/PVDF, the improvements on the energy storage performance in mBT2/PVDF are significant. The maximum discharged energy density of 11.27 J/cm(3) for 4 vol% loading mBT-21 PVDF is nearly double of that for 4 vol% loading BT/PVDF, and the energy efficiency for mBT-2/PVDF is also increased. The modification method originally represented here has great potential in developing high energy density nanocomposites for advanced applications. (C) 2017 Elsevier Ltd. All rights reserved.