Porphyrin-Amino Acid Conjugates

被引：7
|
作者：
Urbanska, Karolina [1 ]
Pawlicki, Milosz [1 ]
机构：
[1] Uniwersytet Wroclawski, Wydzial Chem, PL-50383 Wroclaw, Poland
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 85卷 / 12期
关键词：
SUBSTITUTED PORPHYRINS; EFFICIENT SYNTHESIS; FUSED PORPHYRINS; MESO; FACILE; SUBPORPHYRINS; AMINATION;
D O I：
10.1021/acs.joc.0c00335
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient way for the formation of a direct bond between a porphyrin and amino acid through a main chain nitrogen has been optimized and applied in the synthesis of a library of chromophore-amino acid conjugates with slightly modified and adjustable optical properties. The obtained series of hybrid materials shows an optic response characteristic for meso-nitrogen derivatized porphyrinoids. The oxidation with hypervalent iodine shows a regioselective transformation of an amino acid chain changing the character of the final molecule.
引用
收藏
页码：8196 / 8202
页数：7
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