New synthesis of a soluble high molecular weight poly(arylene vinylene):: Poly[2-methoxy-5-(3,7-dimethyloctyloxy)-p-phenylene vinylene].: Polymerization and device properties

被引：63
作者：
Lutsen, L
Adriaensens, P
Becker, H
Van Breemen, AJ
Vanderzande, D
Gelan, J
机构：
[1] Univ Limburg, Lab Organ & Polymer Chem, Inst Mat Res, Div Chem, B-3590 Diepenbeek, Belgium
[2] Cov Organ Semiconductors GmbH, D-65926 Frankfurt, Germany
来源：
MACROMOLECULES | 1999年 / 32卷 / 20期
关键词：
D O I：
10.1021/ma9904666
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel synthetic approach to high molecular weight poly(arylene vinylene) derivatives has been investigated. Soluble precursors of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-p-phenylenevinylene called OC1C10, were synthesized via a nonionic route. The precursor and the conjugated polymer are discussed along with the electroluminescence and photoluminescence of the latter.
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页码：6517 / 6525
页数：9
相关论文
共 19 条
[1]  
BONG RC, 1993, J CHEM SOC CHEM COMM, P564
[2]   PHOTOLUMINESCENCE AND ELECTROLUMINESCENCE EFFICIENCY IN POLY(DIALKOXY-P-PHENYLENEVINYLENE) [J].
BRAUN, D ;
STARING, EGJ ;
DEMANDT, RCJE ;
RIKKEN, GLJ ;
KESSENER, YARR ;
VENHUIZEN, AHJ .
SYNTHETIC METALS, 1994, 66 (01) :75-79
[3]   IMPROVED EFFICIENCY IN SEMICONDUCTING POLYMER LIGHT-EMITTING-DIODES [J].
BRAUN, D ;
HEEGER, AJ ;
KROEMER, H .
JOURNAL OF ELECTRONIC MATERIALS, 1991, 20 (11) :945-948
[4]   VISIBLE-LIGHT EMISSION FROM SEMICONDUCTING POLYMER DIODES [J].
BRAUN, D ;
HEEGER, AJ .
APPLIED PHYSICS LETTERS, 1991, 58 (18) :1982-1984
[5]   THE EFFECT OF RADICAL TRAPPING REAGENTS UPON FORMATION OF POLY(ALPHA-TETRAHYDROTHIOPHENIO PARA-XYLYLENE) POLYELECTROLYTES BY THE WESSLING SOLUBLE PRECURSOR METHOD [J].
DENTON, FR ;
LAHTI, PM ;
KARASZ, FE .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (10) :2223-2231
[6]  
DOI S, 1993, SYNTHETIC MET, V57, P4174, DOI 10.1016/0379-6779(93)90577-J
[7]   Polymerization of a p-quinodimethane derivative to a precursor of poly(p-phenylene vinylene) - Indications for a free radical mechanism [J].
Issaris, A ;
Vanderzande, D ;
Gelan, J .
POLYMER, 1997, 38 (10) :2571-2574
[8]   SYNTHESIS OF POLY-P-XYLYLIDENE FROM P-XYLYLENE-BIS(DIMETHYLSULFONIUM) TETRAFLUOROBORATE [J].
KANBE, M ;
OKAWARA, M .
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1968, 6 (4PA1) :1058-&
[9]  
Kraft A, 1998, ANGEW CHEM INT EDIT, V37, P402, DOI 10.1002/(SICI)1521-3773(19980302)37:4<402::AID-ANIE402>3.0.CO
[10]  
2-9
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