Application of Taylor Vortex to Crystallization

被引:36
作者
Kim, Woo-Sik [1 ]
机构
[1] Kyung Hee Univ, Dept Chem Engn, Yongin 449701, Kyungki Do, South Korea
关键词
Taylor Vortex; Crystallization; Nucleation; Polymorph; Flexibility; CONTINUOUS EMULSION POLYMERIZATION; ROTATING MEMBRANE-FILTER; GAS-LIQUID REACTION; COUETTE-TAYLOR; PHASE-TRANSFORMATION; GUANOSINE; 5-MONOPHOSPHATE; PHOTOCATALYTIC REACTOR; DYNAMIC SEPARATION; MASS-TRANSFER; FLOW;
D O I
10.1252/jcej.13we143
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study summarizes crystallization technology when using a Taylor vortex flow. A Taylor vortex is created in the gap between two co-axially positioned cylinders based on the rotation of the inner cylinder. Due to its unique periodic flow motion, a Taylor vortex has a significant influence on the processes of nucleation, growth, and agglomeration breakage in various crystallizations, including reaction recrystallization, drowning-out crystallization, and cooling crystallization. In the gas-liquid reaction crystallization of calcium carbonate, the mass transfer at the gas-liquid interface is greatly facilitated by a Taylor vortex, resulting in small crystals with a uniform size and morphology. Further, due to molecular alignment by the periodic Taylor vortex motion, the polymorphic nucleation of stable crystals is also promoted. This effect of molecular alignment by a Taylor vortex is demonstrated by the phase transformation of sulfamerazine. Furthermore, the Taylor vortex flow in a Taylor crystallizer improves the productivity of crystallization when compared with the random turbulent eddy flow in an MSMPR crystallizer. Consequently, the high performance of a Taylor crystallizer using a Taylor vortex has strong potential for application to various crystallizations.
引用
收藏
页码:115 / 123
页数:9
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