Bronsted Acid Generation over Alumina-Supported Niobia by Calcination at 1173 K

被引:32
作者
Shishido, Tetsuya [1 ]
Kitano, Tomoyuki [1 ]
Teramura, Kentaro [2 ]
Tanaka, Tsunehiro [1 ]
机构
[1] Kyoto Univ, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kyoto Univ, Kyoto Univ Pioneering Res Unit Next Generat, Nishikyo Ku, Kyoto 6158510, Japan
关键词
Alumina-supported niobia; Bronsted acid catalyst; Fridel-Crafts reaction; FRIEDEL-CRAFTS ALKYLATION; V METAL-OXIDES; MOLECULAR-STRUCTURE; HETEROPOLY ACID; CATALYSTS; ANISOLE; REACTIVITY;
D O I
10.1007/s10562-008-9837-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alumina-supported niobium oxide promotes Friedel-Crafts reaction of benzyl alcohol and anisole effectively. The optimized condition of the catalyst was 16 wt% as Nb2O5 and calcination temperature of 1173 K. The catalyst exhibits the Bronsted acidity despite calcination at such high temperatures.
引用
收藏
页码:383 / 386
页数:4
相关论文
共 17 条
[1]  
BERZETTI T, 1996, J CHEM SOC FARADAY T, V92, P1401
[2]   CHARACTERIZATION OF CLAY-BASED K-CATALYSTS AND THEIR APPLICATION IN FRIEDEL-CRAFTS ALKYLATION OF AROMATICS [J].
CSERI, T ;
BEKASSY, S ;
FIGUERAS, F ;
CSEKE, E ;
DEMENORVAL, LC ;
DUTARTRE, R .
APPLIED CATALYSIS A-GENERAL, 1995, 132 (01) :141-155
[3]   Liquid phase alkylation of anisole by benzyl alcohol catalyzed on alumina-supported niobia [J].
de la Cruz, Marcus H. C. ;
Abdel-Rehim, Mona A. ;
Rocha, Angela S. ;
da Silva, Joao F. C. ;
Faro, Arnaldo da Costa, Jr. ;
Lachter, Elizabeth R. .
CATALYSIS COMMUNICATIONS, 2007, 8 (11) :1650-1654
[4]   Catalytic activity of niobium phosphate in the Friedel-Crafts reaction of anisole with alcohols [J].
de la Cruz, Marcus Henrique C. ;
da Silva, Joao F. C. ;
Lachter, Elizabeth R. .
CATALYSIS TODAY, 2006, 118 (3-4) :379-384
[5]   Niobium compounds: Preparation, characterization, and application in heterogeneous catalysis [J].
Nowak, I ;
Ziolek, M .
CHEMICAL REVIEWS, 1999, 99 (12) :3603-3624
[6]   Water-tolerant solid acid catalysts [J].
Okuhara, T .
CHEMICAL REVIEWS, 2002, 102 (10) :3641-3665
[7]   The active and reusable catalysts in the benzylation of anisole derived from a heteropoly acid [J].
Okumura, K ;
Yamashita, K ;
Hirano, M ;
Niwa, M .
JOURNAL OF CATALYSIS, 2005, 234 (02) :300-307
[8]   Active and reusable catalyst in the friedel-crafts alkylation derived from a heteropoly acid [J].
Okumura, K ;
Yamashita, K ;
Hirano, M ;
Niwa, M .
CHEMISTRY LETTERS, 2005, 34 (05) :716-717
[9]   Preparation and characterization of niobium oxide for the catalytic aldol condensation of acetone [J].
Paulis, M ;
Martín, M ;
Soria, DB ;
Díaz, A ;
Odriozola, JA ;
Montes, M .
APPLIED CATALYSIS A-GENERAL, 1999, 180 (1-2) :411-420
[10]   Efficient utilization of nanospace of layered transition metal oxide HNbMoO6 as a strong, water-tolerant solid acid catalyst [J].
Tagusagawa, Caio ;
Takagaki, Atsushi ;
Hayashi, Shigenobu ;
Domen, Kazunari .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (23) :7230-+