Optical properties of silica MFI doped acrylamide-based photopolymer

被引:16
作者
Babeva, T. [1 ,2 ]
Todorov, R. [2 ]
Mintova, S. [3 ]
Yovcheva, T. [4 ]
Naydenova, I. [1 ]
Toal, V. [1 ,5 ]
机构
[1] Dublin Inst Technol, Ctr Ind & Engn Opt, Dublin 8, Ireland
[2] Bulgarian Acad Sci, Cent Lab Photoproc, Sofia 1113, Bulgaria
[3] CNRS, UMR 7016, Lab Mat Porosite Controlee, F-68093 Mulhouse, France
[4] Paisij Hilendarski Univ Plovdiv, Dept Expt Phys, BG-4000 Plovdiv, Bulgaria
[5] Dublin Inst Technol, Sch Phys, Dublin 8, Ireland
来源
JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS | 2009年 / 11卷 / 02期
基金
爱尔兰科学基金会;
关键词
optical properties; photopolymer composites; zeolites; porosity; scattering; FILMS; DIFFRACTION; CONSTANTS; BEHAVIOR;
D O I
10.1088/1464-4258/11/2/024015
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The optical properties of acrylamide-based photopolymer doped with pure silica MFI-type zeolites are studied by refractometric and spectrophotometric means. Dynamic light scattering and transmission electron microscopy are used for zeolite characterization, and laser refractometry and white light interferometric profilometry are used for surface characterization of the composites. The refractive indices and absorption coefficients of the composites are determined from their transmittance and reflectance spectra. The calculated dispersion curves are further used for deriving the zeolite's refractive index and porosity, and the porosity is compared to the values of total pore volume obtained from N-2-sorption measurements. The impact of the doping level on the composite's optical properties both on the surface and in the volume are discussed.
引用
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页数:8
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