A polymeric-semiconductor-metal-complex hybrid photocatalyst for visible-light CO2 reduction

被引：242

作者：

Maeda, Kazuhiko ^{[1
,2
]}

Sekizawa, Keita ^{[1
]}

Ishitani, Osamu ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Grad Sch Sci & Engn, Meguro Ku, Tokyo 1528550, Japan

[2] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTU, Kawaguchi, Saitama 3320012, Japan

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 86期

关键词：

GRAPHITIC CARBON NITRIDE; ARTIFICIAL PHOTOSYNTHESIS; PHOTOCHEMICAL REDUCTION; WATER; HYDROGEN; ELECTROCATALYST; SELECTIVITY; DIOXIDE;

D O I：

10.1039/c3cc45532g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polymeric carbon nitride semiconductor is demonstrated to photocatalyse CO2 reduction to formic acid under visible light (lambda > 400 nm) with a high turnover number (>200 for 20 hours) and selectivity (>80%), when coupled with a molecular ruthenium complex as a catalyst.

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收藏

页码：10127 / 10129

页数：3

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