High-throughput experimentation in synthetic polymer chemistry: From RAFT and anionic polymerizations to process development

被引:38
作者
Guerrero-Sanchez, C
Paulus, RM
Fijten, MWM
de la Mar, MJ
Hoogenboom, R
Schubert, US
机构
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Eindhoven Univ Technol, Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands
关键词
high-throughput experimentation; combinatorial material research; RAFT polymerization; anionic polymerization; free radical polymerization;
D O I
10.1016/j.apsusc.2005.05.088
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The application of combinatorial and high-throughput approaches in polymer research is described. An overview of the utilized synthesis robots is given, including different parallel synthesizers and a process development robot. In addition, the application of the parallel synthesis robots to reversible addition fragmentation termination (RAFT) radical polymerizations and ionic copolymerizations is overviewed. Moreover, first results concerning the process development of semi-batch free radical polymerizations are described. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:2555 / 2561
页数:7
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