Aryl-aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes

被引：123

作者：

Belger, Christian ^{[1
]}

Plietker, Bernd ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 44期

关键词：

COMPLEXES; RHODIUM; EFFICIENT; ALKENES; SILICON; A-4; ALKENYLSILANES; HYDROSILATION; LIGANDS; BEARING;

D O I：

10.1039/c2cc31395b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The defined Fe hydride complex FeH(CO)(NO)(Ph3P)(2) is highly active as a catalyst for selective hydrosilylation of internal alkynes to vinylsilanes. Depending on the silane employed either E- or Z-selective hydrosilylation products were formed in excellent yields and good to excellent stereoselectivities.

引用

页码：5419 / 5421

页数：3

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