Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]•dmf (abzt=2-aminobenzothiazole), trans-[PdCl2(bzta)2]•dmf (bzta=2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]•2dmf

被引：20

作者：

Al-Jibori, Subhi A. ^{[1
]}

Habeeb, Adnan T. ^{[1
]}

Al-Jibori, Ghassan H. H. ^{[1
]}

Dayaaf, Noor A. ^{[1
]}

Merzweiler, Kurt ^{[2
]}

Wagner, Christoph ^{[2
]}

Schmidt, Harry ^{[2
]}

Hogarth, Graeme ^{[3
]}

机构：

[1] Univ Tikrit, Dept Chem, Coll Sci, Tikrit, Iraq

[2] Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Germany

[3] UCL, Dept Chem, London WC1H 0AJ, England

来源：

POLYHEDRON | 2014年 / 67卷

关键词：

Palladium; Aminothiazole; Saccharinate; Thiosaccharinate; X-ray studies; PLATINUM(II) COMPLEXES; MOLECULAR-STRUCTURES; IN-VITRO; BINDING; DNA;

D O I：

10.1016/j.poly.2013.09.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Na2PdCl4 with two equivalents of amino- or acetylamino-thiazoles [L = 2-aminobenzothiazole (abzt), 2-aminothiazole (atz), 2-acetylaminobenzothiazole (bzta) and 2-acetylaminothiazole (tza)] or 2-aminobenzimidazole (abzim)] affords trans-[PdCl2L2] complexes in which the introduced ligands are coordinated to palladium through the endocyclic nitrogen as shown by X-ray crystal structures of trans-[PdCl2(abzt)(2)]center dot dmf and trans-[PdCl2(bzta)(2)]center dot dmf. Addition of two equivalents of sodium saccharinate (Nasac) yields trans-[Pd(sac)(2)L-2] complexes whereby the saccharinate anions are coordinated through nitrogen as shown by the X-ray crystal structure of trans-[Pd(sac)(2)(abtz)(2)]center dot 2dmf. With thiosac-charin (I-Itsac) trans-[Pd(tsac)(2)L-2] result but now the thiosaccharinate ligands coordinate through the sulfur of the thiolate group as evidenced by spectroscopic studies. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：338 / 343

页数：6

共 28 条

[1] Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with 2-aminopyridine (2-ampy), 2-acetylaminopyridine (2-aampy) and 2-acetylaminopyrimidine (2-aampym) co-ligands: X-ray crystal structures of trans-[Pd(sac)2(ampy)2] and solvatomorphs trans-[Pd(sac)2(2-aampy)2].S (S = CHCl3, thf) [J].