Study of high-energy radiation initiated polymerization of butyl acrylate

被引：7

作者：

Takács, E ^{[1
]}

Dajka, K ^{[1
]}

Wojnárovits, L ^{[1
]}

机构：

[1] Hungarian Acad Sci, Inst Isotopes & Surface Chem, Chem Res Ctr, H-1525 Budapest, Hungary

来源：

RADIATION PHYSICS AND CHEMISTRY | 2002年 / 63卷 / 01期

关键词：

polymerization kinetics; rate coefficient of termination; pulse radiolysis; high-energy radiation;

D O I：

10.1016/S0969-806X(01)00479-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics and mechanism of the first steps of radiation initiated polymerization was studied in cyclohexane solution of butyl acrylate applying pulse radiolysis with optical detection. By increasing the monomer concentration, the shape and wavelength of the maximum of the spectrum was changed indicating the start of the oligomerization reaction. From the kinetic curves average rate coefficients of termination for the oligomer radicals (2k(t)) were determined. They were found to decrease in time (that is with increasing chain-length). (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：41 / 44

页数：4

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