Protection of epoxy coatings containing polyaniline modified ultra-short glass fibers

被引:84
作者
Hao, Yongsheng [1 ]
Liu, Fuchun [1 ]
Han, En-Hou [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
基金
中国博士后科学基金;
关键词
Organic coatings; EIS; SEM; XPS; Passivity; CORROSION PROTECTION; ANTICORROSION PROPERTIES; FLEXURAL PROPERTIES; DOPED POLYANILINE; ORGANIC COATINGS; MAGNESIUM ALLOY; EMERALDINE BASE; BIPOLAR FILMS; CARBON-STEEL; MILD-STEEL;
D O I
10.1016/j.porgcoat.2012.11.012
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Polyaniline (PANI) was covered on the surface of ultra-short glass fibers uniformly by in situ polymerization of aniline. Epoxy coatings with different contents of PANI ultra-short glass fibers and ultra-short glass fibers were formulated and their protection abilities were evaluated by means of open-circuit potential, electrochemical impedance spectroscopy and salt spray test. The results showed that the PANI ultra-short glass fibers had a significant inhibitive effect and its best volume fraction was 10% in epoxy coating. XPS results indicated that a dense, stable passive oxide film of Fe2O3/Fe3O4 was formed on the steel surface beneath the coating. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:571 / 580
页数:10
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