Enhanced tunneling conductivity induced by gelation of attractive colloids

被引:10
作者
Nigro, Biagio [1 ]
Grimaldi, Claudio [1 ]
Ryser, Peter [1 ]
Varrato, Francesco [2 ]
Foffi, Giuseppe [2 ,3 ]
Lu, Peter J. [4 ,5 ]
机构
[1] Ecole Polytech Fed Lausanne, LPM, CH-1015 Lausanne, Switzerland
[2] Ecole Polytech Fed Lausanne, Inst Theoret Phys, CH-1015 Lausanne, Switzerland
[3] Univ Paris 11, UMR 8502, Phys Solides Lab, F-91405 Orsay, France
[4] Harvard Univ, Dept Phys, Cambridge, MA 02138 USA
[5] Harvard Univ, SEAS, Cambridge, MA 02138 USA
来源
PHYSICAL REVIEW E | 2013年 / 87卷 / 06期
基金
瑞士国家科学基金会;
关键词
PERCOLATION; PARTICLES;
D O I
10.1103/PhysRevE.87.062312
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We show that the formation of a gel by conducting colloidal particles leads to a dramatic enhancement in bulk conductivity, due to interparticle electron tunneling, combining predictions from molecular-dynamics simulations with structural measurements in an experimental colloid system. Our results show how colloidal gelation can be used as a general route to huge enhancements of conductivity, and suggest a feasible way for developing cheap materials with novel properties and low metal content.
引用
收藏
页数:8
相关论文
共 35 条
  • [1] HOPPING CONDUCTIVITY IN DISORDERED SYSTEMS
    AMBEGAOKAR, V
    HALPERIN, BI
    LANGER, JS
    [J]. PHYSICAL REVIEW B-SOLID STATE, 1971, 4 (08): : 2612 - +
  • [2] Solution of the tunneling-percolation problem in the nanocomposite regime
    Ambrosetti, G.
    Grimaldi, C.
    Balberg, I.
    Maeder, T.
    Danani, A.
    Ryser, P.
    [J]. PHYSICAL REVIEW B, 2010, 81 (15)
  • [3] Insights into phase transition kinetics from colloid science
    Anderson, VJ
    Lekkerkerker, HNW
    [J]. NATURE, 2002, 416 (6883) : 811 - 815
  • [4] PERCUS-YEVICK EQUATION FOR HARD SPHERES WITH SURFACE ADHESION
    BAXTER, RJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (06) : 2770 - &
  • [5] Interplay between spinodal decomposition and glass formation in proteins exhibiting short-range attractions
    Cardinaux, Frederic
    Gibaud, Thomas
    Stradner, Anna
    Schurtenberger, Peter
    [J]. PHYSICAL REVIEW LETTERS, 2007, 99 (11)
  • [6] Slow dynamics in glassy soft matter
    Cipelletti, L
    Ramos, L
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (06) : R253 - R285
  • [7] Aggregation of model gels with directional interactions
    Del Gado, E.
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2010, 22 (10)
  • [8] PERCOLATION ON A SELF-ASSEMBLED NETWORK - DECORATION OF POLYETHYLENE GELS WITH CONDUCTING POLYMER
    FIZAZI, A
    MOULTON, J
    PAKBAZ, K
    RUGHOOPUTH, SDDV
    SMITH, P
    HEEGER, AJ
    [J]. PHYSICAL REVIEW LETTERS, 1990, 64 (18) : 2180 - 2183
  • [9] Arrested phase separation in a short-ranged attractive colloidal system: A numerical study
    Foffi, G
    De Michele, C
    Sciortino, F
    Tartaglia, P
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2005, 122 (22)
  • [10] Scaling of dynamics with the range of interaction in short-range attractive colloids
    Foffi, G
    De Michele, C
    Sciortino, F
    Tartaglia, P
    [J]. PHYSICAL REVIEW LETTERS, 2005, 94 (07)