From terpenes to sustainable and functional polymers

被引：165
作者：
Della Monica, Francesco [1 ]
Kleij, Arjan W. [1 ,2 ]
机构：
[1] Barcelona Inst Sci & Technol BIST, Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain
[2] Catalan Inst Res & Adv Studies ICREA, Pg Lluis Co 23, Barcelona 08010, Spain
来源：
POLYMER CHEMISTRY | 2020年 / 11卷 / 32期
基金：
欧盟地平线“2020”;
关键词：
RING-OPENING COPOLYMERIZATION; BIO-BASED CHEMICALS; CARBON-DIOXIDE; ALTERNATING COPOLYMERIZATION; LIMONENE OXIDE; ALPHA-PINENE; THERMOPLASTIC ELASTOMERS; CATIONIC-POLYMERIZATION; PROPYLENE-OXIDE; BIORENEWABLE POLYESTERS;
D O I：
10.1039/d0py00817f
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Our dependence on fossil-fuel based raw materials and alarming plastics accumulation in the environment has inspired many scientists to design and implement more sustainable approaches for polymer synthesis. The identification and assessment of new and renewable biobased monomers has become a major topic of interesten routeto a circular economy. In this respect, terpenes and terpenoid scaffolds have attracted much attention due to their ubiquitous nature and high functionality. This minireview uncovers recent advancements in the synthesis of terpene-based polymers, and specifically discusses the formation of terpene-derived polycarbonates, polyesters, polyurethanes and polyamides. The potential of these polymers in post-synthetic curing and modifications is also highlighted to illustrate the opportunities that exist to develop new polymer formulations beyond bench scale.
引用
收藏
页码：5109 / 5127
页数：19
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