A Selective and Ratiometric Bifunctional Fluorescent Probe for Al3+ Ion and Proton

被引:235
作者
Sun, Xin
Wang, Ya-Wen
Peng, Yu [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China
关键词
CHELATION-ENHANCED FLUORESCENCE; 1,1'-BINAPHTHYL SCAFFOLD; ALUMINUM ACCUMULATION; AQUEOUS-MEDIA; SENSOR; PH; CHEMOSENSOR; CELLS; CU2+; CHEMODOSIMETER;
D O I
10.1021/ol301390g
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new bifunctional probe based on a pyrene amino acid conjugate for the differential response of Al3+ and H+ was demonstrated for the first time. Interestingly, two solvent-dependent sensing mechanisms for Al3+, which feature a ratiometric change from excimer to monomer in CH3OH and a turn-on response in water, are also disclosed.
引用
收藏
页码:3420 / 3423
页数:4
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