Synthesis and characterization of a new framework cobalt phosphate with one-dimensional channel, Co3(H2O)4(PO4)2

被引：2
|
作者：
Lin, Yuan [1 ]
Ning, Guiling [1 ]
Ye, Junwei [1 ]
Fan, Yong [2 ]
Wang, Li [1 ,2 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130012, Jilin, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 6-7期
关键词：
cobalt; cobalt phosphate; crystal structure; hydrothermal synthesis;
D O I：
10.1002/zaac.200700590
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new cobalt phosphate, Co-3(H2O)(4)(PO4)(2) (1) has been synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction. Crystal data for 1: orthorhombic system, Pnma, a = 10. 582(2) angstrom, b = 18.289(4) angstrom, c = 5.0236(10) angstrom, V = 972.2(3) angstrom(3), Z = 4. The compound displays complex threedimensional framework containing one-dimensional 8-membered ring channels. In this crystal structure, CoO4 and PO4 tetrahedra connect each other by sharing-vertex to form the infinite two-dimensional sheet which contains the edge-sharing four ring chain and double zig-zag chain, then these sheets are pillared by CoO2(H2O)(4) octahedra.
引用
收藏
页码：1145 / 1148
页数：4
相关论文
共 50 条
  • [41] Ramazzoite, [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36], the first mineral with a polyoxometalate cation
    Kampf, Anthony R.
    Rossman, George R.
    Ma, Chi
    Belmonte, Donato
    Biagioni, Cristian
    Castellaro, Fabrizio
    Chiappino, Luigi
    EUROPEAN JOURNAL OF MINERALOGY, 2018, 30 (04) : 827 - 834
  • [42] The synthesis and crystal structure of a hydrated magnesium phosphate Mg3(PO4)2•4H2O
    Kongshaug, KO
    Fjellvåg, H
    Lillerud, KP
    SOLID STATE SCIENCES, 2001, 3 (03) : 353 - 359
  • [43] New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2
    Kim, Min Kyung
    Kim, Sang-Hwan
    Chang, Hong-Young
    Halasyamani, P. Shiv
    Ok, Kang Min
    INORGANIC CHEMISTRY, 2010, 49 (15) : 7028 - 7034
  • [44] A new sodium hydroxygallophosphate containing tetrameric gallium units:: Na3[Ga4O(OH)(H2O)(PO4)4] • H2O
    Guesdon, A
    Monnin, Y
    Raveau, B
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (01) : 181 - 188
  • [45] Hydrothermal synthesis and crystal structure of a three-dimensional compound {Mn(H2O)4(VO)2(PO4)2}n
    Wu, Y
    Jiang, XY
    Zhang, QZ
    Chen, LJ
    Yu, YQ
    Chen, SM
    He, X
    Yang, WB
    Lu, CZ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (03) : 291 - 294
  • [46] Hydrothermal synthesis and characterization of two mixed valence piperazine-vanadium phosphates:: (C4H12N2)(H3O)[(VOPO4)4(H2O)H2PO4]•3H2O and (C4H12N2)[(VO)(VO2)2(H2O)(PO4)2]
    Do, J
    Bontchev, RP
    Jacobson, AJ
    JOURNAL OF SOLID STATE CHEMISTRY, 2000, 154 (02) : 514 - 523
  • [47] Ni3Te2O2(PO4)2(OH)4, an open-framework structure isotypic with Co3Te2O2(PO4)2(OH)4
    Eder, Felix
    Weil, Matthias
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 625 - +
  • [48] Potassium nickel(II) gallium phosphate hydrate, K[NiGa2(PO4)3(H2O)2]
    Chippindale, Ann M.
    Sharma, Arun V.
    Hibble, Simon J.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : I38 - U167
  • [49] Hydrothermal Synthesis and Crystal Structure of a Three-dimensional Compound {Mn（H2O）4（VO）2（PO4）2}n
    WU Yanga JIANG Xiao-Yub ZHANG Quan-Zhengc CHEN Li-Juanc YU Ya-Qinc CHEN Shu-Meic HE Xiangc YANG Wen-Binc LU Can-Zhongc② a(College of Chemistry & Materials Science
    Chinese Journal of Structural Chemistry, 2005, (03) : 291 - 294
  • [50] Hydrothermal synthesis and characterization of Na3Y(PO4)2 phosphate
    Matraszek, Aleksandra
    Szczygiel, Irena
    Szczygiel, Bogdan
    JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 612 : 411 - 417
12345