Synthesis and characterization of a new framework cobalt phosphate with one-dimensional channel, Co3(H2O)4(PO4)2

被引：2
|
作者：
Lin, Yuan [1 ]
Ning, Guiling [1 ]
Ye, Junwei [1 ]
Fan, Yong [2 ]
Wang, Li [1 ,2 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130012, Jilin, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 6-7期
关键词：
cobalt; cobalt phosphate; crystal structure; hydrothermal synthesis;
D O I：
10.1002/zaac.200700590
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new cobalt phosphate, Co-3(H2O)(4)(PO4)(2) (1) has been synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction. Crystal data for 1: orthorhombic system, Pnma, a = 10. 582(2) angstrom, b = 18.289(4) angstrom, c = 5.0236(10) angstrom, V = 972.2(3) angstrom(3), Z = 4. The compound displays complex threedimensional framework containing one-dimensional 8-membered ring channels. In this crystal structure, CoO4 and PO4 tetrahedra connect each other by sharing-vertex to form the infinite two-dimensional sheet which contains the edge-sharing four ring chain and double zig-zag chain, then these sheets are pillared by CoO2(H2O)(4) octahedra.
引用
收藏
页码：1145 / 1148
页数：4
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