Synthesis of an imprinted polymer for the determination of methylmercury in marine products

被引：15
作者：
Rodriguez-Fernandez, Roi [1 ]
Pena-Vazquez, Elena [1 ]
Bermejo-Barrera, Pilar [1 ]
机构：
[1] Univ Santiago de Compostela, Fac Chem, Dept Analyt Chem Nutr & Bromatol, E-15782 Santiago De Compostela, Spain
来源：
TALANTA | 2015年 / 144卷
关键词：
Methylmercury; Molecularly imprinted polymer (MIP); SPE; HRCSAAS; Fish; HIGHLY SELECTIVE DETERMINATION; GLASSY-CARBON ELECTRODE; MERCURY(II) IONS; PRECONCENTRATION; SEPARATION; SORBENT; REMOVAL; SENSOR; HG2+; EXTRACTION;
D O I：
10.1016/j.talanta.2015.06.028
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A molecularly imprinted polymer was synthesized using the precipitation method with methylmercury chloride as the template, phenobarbital as ligand, methacrylic acid (MMA) as monomer, and ethylene glycoldimethacrylate (EDMA) as cross-linking agent. The MIP was characterized using elemental analysis, infrared spectroscopy, energy dispersive X-ray fluorescence and scanning electron microscopy. The operating conditions for solid phase extraction (SPE) were optimized in column mode (pH, loading and elution flow rate using 1 M thiourea in 1 M HCl). The polymer was used for analyzing the toluene extracts of two reference materials (BCR-463 and TORT-2) with good accuracy. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：636 / 641
页数：6
相关论文
共 42 条
[1]   Scientific Opinion on health benefits of seafood (fish and shellfish) consumption in relation to health risks associated with exposure to methylmercury [J].
Agostoni, Carlo ;
Canani, Roberto Berni ;
Fairweather-Tait, Susan ;
Heinonen, Marina ;
Korhonen, Hannu ;
La Vieille, Sebastien ;
Marchelli, Rosangela ;
Martin, Ambroise ;
Naska, Androniki ;
Neuhaeuser-Berthold, Monika ;
Nowicka, Grazyna ;
Sanz, Yolanda ;
Siani, Alfonso ;
Sjoedin, Anders ;
Stern, Martin ;
Strain, Sean ;
Tetens, Inge ;
Tome, Daniel ;
Turck, Dominique ;
Verhagen, Hans .
EFSA JOURNAL, 2014, 12 (07)
[2]   Application of an Hg2+ selective imprinted polymer as a new modifying agent for the preparation of a novel highly selective and sensitive electrochemical sensor for the determination of ultratrace mercury ions [J].
Alizadeh, Taher ;
Ganjali, Mohamad Reza ;
Zare, Mashaalah .
ANALYTICA CHIMICA ACTA, 2011, 689 (01) :52-59
[3]   Ion-imprinted beads for molecular recognition based mercury removal from human serum [J].
Andac, Muge ;
Mirel, Sinem ;
Senel, Serap ;
Say, Ridvan ;
Ersoz, Arzu ;
Denizli, Adil .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2007, 40 (02) :159-166
[4]  
[Anonymous], 2002, Global Mercury Assessment
[5]  
AOAC, 2005, OFF METH AN, V15th, P40
[6]   Imprinted polymers for the removal of heavy metal ions from water [J].
Ashraf, Syed ;
Cluley, Angela ;
Mercado, Ckarlos ;
Mueller, Anja .
WATER SCIENCE AND TECHNOLOGY, 2011, 64 (06) :1325-1332
[7]   An ion-imprinted polymer for the selective extraction of mercury(II) ions in aqueous media [J].
Batlokwa, Bareki S. ;
Chimuka, Luke ;
Tshentu, Zenixole ;
Cukrowska, Ewa ;
Torto, Nelson .
WATER SA, 2012, 38 (02) :255-260
[8]   Scientific Opinion on the risk for public health related to the presence of mercury and methylmercury in food [J].
Benford, Diane ;
Ceccatelli, Sandra ;
Cottrill, Bruce ;
DiNovi, Michael ;
Dogliotti, Eugenia ;
Edler, Lutz ;
Farmer, Peter ;
Fuerst, Peter ;
Hoogenboom, Laurentius ;
Knutsen, Helle Katrine ;
Haldorsen, Anne-Katrine Lundebye ;
Metzler, Manfred ;
Nebbia, Carlo Stefano ;
O'Keeffe, Michael ;
Rietjens, Ivonne ;
Schrenk, Dieter ;
Silano, Vittorio ;
van Loveren, Hendrik ;
Vleminckx, Christiane ;
Wester, Pieter .
EFSA JOURNAL, 2012, 10 (12)
[9]   Recent advances on ion-imprinted polymers [J].
Branger, Catherine ;
Meouche, Walid ;
Margaillan, Andre .
REACTIVE & FUNCTIONAL POLYMERS, 2013, 73 (06) :859-875
[10]   Mimicking receptor for methylmercury preconcentration based on ion-imprinting [J].
Buyuktiryaki, Sibel ;
Say, Ridvan ;
Denizli, Adil ;
Ersoz, Arzu .
TALANTA, 2007, 71 (02) :699-705
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