A cell for in situ x-ray diffraction based on coin cell hardware and Bellcore plastic electrode technology

被引:81
作者
Richard, MN
Koetschau, I
Dahn, JR
机构
[1] Department of Physics, Simon Fraser University, Burnaby
[2] Department of Physics, Dalhousie University, Halifax
关键词
D O I
10.1149/1.1837447
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In situ x-ray diffraction has been shown to be a powerful tool for the study of the crystallographic changes that occur in a material as intercalation proceeds. Here we report the development of an zn situ cell based on coin cell hardware and Bellcore plastic electrode technology. The coin cell hardware makes construction very simple, the cells seal well and cycle just as regular coin cells do. Therefore extended in situ x-ray studies as a function of cycle number are now possible. We demonstrate the new design with preliminary experiments on LiMnO2 and LiMn2O4.
引用
收藏
页码:554 / 557
页数:4
相关论文
共 8 条
[1]   CoO2, the end member of the LixCoO2 solid solution [J].
Amatucci, GG ;
Tarascon, JM ;
Klein, LC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (03) :1114-1123
[2]   HIGH-PRECISION STUDIES OF LATTICE-PARAMETER CHANGES IN LITHIUM INTERCALATION COMPOUNDS [J].
DAHN, JR ;
MCKINNON, WR .
SOLID STATE IONICS, 1984, 14 (02) :131-136
[3]   INSITU X-RAY-DIFFRACTION EXPERIMENTS ON LITHIUM INTERCALATION COMPOUNDS [J].
DAHN, JR ;
PY, MA ;
HAERING, RR .
CANADIAN JOURNAL OF PHYSICS, 1982, 60 (03) :307-313
[4]   LARGE LITHIUM POLYMER BATTERY DEVELOPMENT - THE IMMOBILE SOLVENT CONCEPT [J].
GAUTHIER, M ;
BELANGER, A ;
BOUCHARD, P ;
KAPFER, B ;
RICARD, S ;
VASSORT, G ;
ARMAND, M ;
SANCHEZ, JY ;
KRAUSE, L .
JOURNAL OF POWER SOURCES, 1995, 54 (01) :163-169
[5]  
GOZDZ AS, 1994, Patent No. 8772
[6]   ORTHORHOMBIC LIMNO2 AS A HIGH-CAPACITY CATHODE FOR LI-ION CELLS [J].
KOETSCHAU, I ;
RICHARD, MN ;
DAHN, JR ;
SOUPART, JB ;
ROUSCHE, JC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (09) :2906-2910
[7]   LITHIUM INSERTION IN CARBONS CONTAINING NANODISPERSED SILICON [J].
WILSON, AM ;
DAHN, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (02) :326-332
[8]   An investigation of lithium ion insertion into spinel structure Li-Mn-O compounds [J].
Xia, YY ;
Yoshio, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (03) :825-833