A Unique Cascade Reaction between 3-Arylprop-2-inylcarboxylates and Benzaldehydes Leading to the Formation of Morita-Baylis-Hillman Adducts

被引：15

作者：

Karpaviciene, Ieva ^{[1
]}

Cikotiene, Inga ^{[1
]}

机构：

[1] Vilnius State Univ, Fac Chem, Dept Organ Chem, LT-03225 Vilnius, Lithuania

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 01期

关键词：

PHENYL VINYL KETONE; ALDEHYDES; ACRYLATE; THIOACRYLATE; DIMERIZATION; CATALYSIS; ALKYNES; BF3;

D O I：

10.1021/ol303319a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

During an alkyne-carbonyl metathesis reaction between electron-rich 3-arylprop-2-inylcarboxylates and electron-poor benzaldehydes, a smooth migration of carboxylate groups takes place. This unique cascade reaction allows the formation of Morita-Baylis-Hillman (MBH) adducts unavailable via a traditional MBH reaction.

引用

页码：224 / 227

页数：4

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