Fabrication of Carbon Nanowalls on Carbon Fiber Paper for Fuel Cell Application

被引:19
作者
Hiramatsu, Mineo [1 ]
Mitsuguchi, Shinji [1 ]
Horibe, Takeyoshi [2 ]
Kondo, Hiroki [2 ]
Hori, Masaru [2 ]
Kano, Hiroyuki [3 ]
机构
[1] Meijo Univ, Dept Elect & Elect Engn, Nagoya, Aichi 4688502, Japan
[2] Nagoya Univ, Dept Elect Engn & Comp Sci, Nagoya, Aichi 4648603, Japan
[3] NU Eco Engn Co Ltd, Miyoshi, Aichi 4700201, Japan
关键词
CHEMICAL-VAPOR-DEPOSITION; PLATINUM NANOPARTICLES; SUPERCRITICAL DEPOSITION; RADICAL INJECTION; ANODE CATALYST; NANOTUBES; PERFORMANCE; GRAPHITE; GROWTH; LAYER;
D O I
10.7567/JJAP.52.01AK03
中图分类号
O59 [应用物理学];
学科分类号
摘要
Carbon nanowalls (CNWs) can be described as self-assembled, vertically standing, few-layered graphene sheet nanostructures. In order to demonstrate the usefulness of CNWs in fuel cell application, CNWs were directly grown on carbon fiber paper (CFP) using the inductively coupled plasma-enhanced chemical vapor deposition (ICP-CVD) method. Subsequently, highly dispersed platinum (Pt) nanoparticles were formed on the surface of CNWs using metal-organic chemical fluid deposition (MOCFD) employing a supercritical fluid (SCF). Moreover, a single proton exchange membrane (PEM) fuel cell unit using a Pt-supported CNW/CFP electrode was constructed, and its voltage-current characteristics were measured. This configuration ensures that all the supported Pt nanoparticles are in electrical contact with the external electrical circuit. Such a design would improve Pt utilization and potentially decrease Pt usage. Pt-supported CNWs grown on CFP will be well suited to the application in electrodes of fuel cells. (C) 2013 The Japan Society of Applied Physics
引用
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页数:5
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