Experimental and computational probes of a self-assembled capsule

被引：15
|
作者：
Iwasawa, Tetsuo
Ajami, Dariush
Rebek, Julius, Jr.
机构：
[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 14期
关键词：
D O I：
10.1021/ol0607600
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This research was undertaken to explore the interior surface of a synthetic receptor 1.1 with arylpyridines as guests. The interior surface differentiates the guests through the recognition of their nitrogen atoms. Experimental and computational analyses revealed that there is a delicate balance of attractions and repulsions between the host and the lone pairs of guests.
引用
收藏
页码：2925 / 2928
页数：4
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