Palladium complexes with PCP ligands.: Preparation and structural studies of two forms of [(PCP)Pd(OH2)]+BF4-

被引：29

作者：

Kimmich, BFM

Marshall, WJ

Fagan, PJ

Hauptman, E

Bullock, RM ^{[1
]}

机构：

[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[2] Dupont Co Inc, Expt Stn, Dept Cent Res & Dev, Wilmington, DE 19880 USA

来源：

INORGANICA CHIMICA ACTA | 2002年 / 330卷

关键词：

palladium complexes; aqua complexes; hydrogen bonding; crystal structures;

D O I：

10.1016/S0020-1693(01)00736-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Abstraction of chloride from the Pd complex {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]PdCl with AgBF4 in THF gives {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]Pd(THF)}+BF4-. Attemped crystallization of this THF complex produced the aqua complex {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]Pd(OH2))+BF4-. Crystal structures of two crystalline forms of this compound are reported. In In {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]Pd(OH2)}(+) BF4- THF, one hydrogen of the water is hydrogen bonded to the oxygen of the THF, and the other hydrogen is hydrogen bonded to an F of the BF4- anion. Another crystalline form has no THF, but has both of the hydrogens of water hydrogen bonded to different BF4- anions, such that two different BF4- anions bridge two {[eta(3)-2,6-((Bu2PCH)-Bu-1)(2)C6H3)]Pd(OH2)}(+) cations. A crystal structure is also reported for the palladium chloride complex [eta(3)-2,6((Bu2PCH2)-Bu-1)(2)C6H3)]PdCl. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：52 / 58

页数：7

共 48 条

[1]

Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO

[2]

2-6

[3] METALLOORGANIC LEWIS-ACIDS .18. HYDRIDOIRIDIUM(III) COMPLEXES WITH THE WEAKLY COORDINATED ANIONS PF6- AND ALCL4- AND THEIR REACTIONS WITH WATER - X-RAY STRUCTURES OF [(PPH3)2(CO)(CL)(H)IR(OH2)]+BF4- AND (PPH3)2(CO)(CL)(H)IROPOF2 [J].