Temperature dependence of the colloidal stability of neutral amphiphilic polymers in water

被引：212
|
作者：
Aseyev, VO
Tenhu, H
Winnik, FM
机构：
[1] Univ Helsinki, Polymer Chem Lab, FIN-00014 Helsinki, Finland
[2] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada
[3] Univ Montreal, Fac Pharm, Montreal, PQ H3C 3J7, Canada
来源：
CONFORMATION-DEPENDENT DESIGN OF SEQUENCES IN COPOLYMERS II | 2006年 / 196卷 / 1-85期
关键词：
colloidal stability; globule; mesoglobule; thermoresponsive polymers;
D O I：
10.1007/12_052
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Various thermally responsive polymers and their derivatives form colloidally stable nanosized particles upon heating of their aqueous solutions. A compilation of the types of polymers reported to exhibit this behaviour is presented in this review, including poly(N-isopropylacrylamide), poly(N-vinylcaprolactam), and poly(vinyl methylether) together with their copolymers with either hydrophobic or hydrophilic monomers. in all cases experimental evidence is presented, together with various theoretical models. Possible mechanisms responsible for the stabilisation of these colloids are discussed.
引用
收藏
页码：1 / 85
页数：85
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