Rational design of a well-defined soluble calcium hydride complex

被引：205
作者：
Harder, Sjoerd [1 ]
Brettar, Julie [1 ]
机构：
[1] Univ Duisburg Gesamthsch, D-45117 Essen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 21期
关键词：
alkaline-earth metals; amides; calcium; hydrides; scorpionate ligands;
D O I：
10.1002/anie.200601013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A surprisingly simple approach led to the synthesis of a molecular calcium hydride. Reaction of a calcium amide with phenylsilane gives clean conversion into the hydride that crystallizes as a dimer (see structure). (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：3474 / 3478
页数：5
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