Photoluminescence from Zinc Oxide Quantum Dots Embedded in Silicon Dioxide Matrices

被引:11
作者
Zhong, Kun [1 ]
机构
[1] Nanjing Univ Informat Sci & Technol, Sch Phys & Optoelect Engn, Nanjing, Jiangsu, Peoples R China
关键词
photoluminescence; SPR defect; ZnO QDS; ZNO; LUMINESCENCE; BAND;
D O I
10.1080/00387010.2012.704475
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
ZnO quantum dots (QDs) embedded in SiO2 matrix are fabricated by ion implantation and annealing treatment methods. When the Zn-doping dose is (2, 3, 5, and 7)x10(16)cm(-2), the size of quantum dots is in the range of approximate to 4-10nm in diameter according to the XRD and HR-TEM results. Ultraviolet and green light emissions from the specimen are obtained at room temperature. With the increase of the Zn-doping dose, the PL peak in the ultraviolet region red shifts from 3.32 to 3.10eV. This PL peak is related to the size of ZnO QDs, which is ascribed to the free exciton recombination in QDs. The green light emissions centered at 2.43 and 2.25eV are independent of the Zn-doping dose and annealing temperature, which are attributed to the deep-level defect and the small peroxy radical (SPR) defect, respectively.
引用
收藏
页码:160 / 164
页数:5
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