Catalytic properties of acid solutions and the structure of acid-base complexes with strong hydrogen bonds

被引：12

作者：

Librovich, NB ^{[1
]}

Kislina, IS ^{[1
]}

机构：

[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia

来源：

KINETICS AND CATALYSIS | 2002年 / 43卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1023/A:1014245028270

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic of acid solutions involves an equilibrium step in the formation of a reactive complex of reactant molecules with catalyst entities. The relative concentrations of these complexes are determined by using thermodynamic parameters (acidity functions and activities of catalyst components). Data on the structure of complexes with strong H-bonds can be obtained from the vibrational spectra of these species. These data are required for establishing the mechanisms of catalytic reactions and for predicting the catalytic properties of acid solutions containing these complexes.

引用

页码：51 / 55

页数：5