Efficient Catalytic System for the Selective Production of 5-Hhydroxymethylfurfural from Glucose and Fructose

被引：358

作者：

Yong, Gen ^{[1
]}

Zhang, Yugen ^{[1
]}

Ying, Jackie Y. ^{[1
]}

机构：

[1] Inst Bioengn & Nanotechnol, Singapore 138669, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 48期

关键词：

biomass; carbenes; carbohydrates; catalysis; ionic liquids;

D O I：

10.1002/anie.200803207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A sweet conversion! A NHC-Cr/ionic liquid system has achieved excellent efficiency and the highest 5-hydroxymethylfurfural (1; see scheme; NHC=N-heterocyclic carbene) yields reported thus far for both fructose and glucose feedstocks. The catalyst and ionic liquid are tolerant of high substrate loading and can be recycled after extraction of the product. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9345 / 9348

页数：4

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