Simultaneous measurement of diazolidinyl urea, urea, and allantoin in cosmetic samples by hydrophilic interaction chromatography

被引:30
作者
Doi, Takahiro [1 ]
Kajimura, Keiji [1 ]
Takatori, Satoshi [1 ]
Fukui, Naoki [1 ]
Taguchi, Shuzo [1 ]
Iwagami, Shozo [1 ]
机构
[1] Osaka Prefectural Inst Publ Hlth, Higashinari Ku, Osaka 5370025, Japan
来源
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES | 2009年 / 877卷 / 10期
关键词
Diazolidinyl urea; Allantoin; Urea; Hydrophilic interaction chromatography; Cosmetic; PERFORMANCE LIQUID-CHROMATOGRAPHY; CONTACT SENSITIVITY; HPLC METHOD; URIC-ACID; FORMALDEHYDE; CREAM; SKIN;
D O I
10.1016/j.jchromb.2009.02.032
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A new HPLC method for simultaneous measurement of diazolidinyl urea (DU), urea, and allantoin by hydrophilic interaction chromatography using a column packed with triazol-bonded silica particles is described. The calibration curves of DU, urea, and allantoin were linear over the ranges 2.5-125.0, 30-1250, and 0.25-18.75 mg/L, respectively. The recoveries of DU, urea, and allantoin from homemade cosmetic samples ranged from 92.84% to 101.69%, 98.19% to 103.22%, and 95.75% to 102.09%, respectively. The peak relative standard deviation (RSD) values for the recovery tests of 3 concentrations/5 replicates were 3.03% for all compounds. In day-to-day measurement of recovery tests from homemade lotions over 3 consecutive days, the RSDs were less than 2.5% in all cases. This method was well validated and would be helpful for quickly analyzing these compounds in cosmetic samples. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1005 / 1010
页数:6
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