The use of lanthanide luminescence as a reporter in the solid state: Desymmetrization of the prochiral layers of γ-zirconium phosphate/phosphonate and circularly polarized luminescence

被引：15
作者：
Brunet, Ernesto [1 ]
Jimenez, Laura [1 ]
de Victoria-Rodriguez, Maria [1 ]
Vinh Luu [2 ]
Muller, Gilles [2 ]
Juanes, Olga [1 ]
Carlos Rodriguez-Ubis, Juan [1 ]
机构：
[1] Univ Autonoma Madrid, Fac Ciencias C1, Dept Quim Organ, E-28049 Madrid, Spain
[2] San Jose State Univ, Dept Chem, San Jose, CA 95192 USA
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2013年 / 169卷
关键词：
Zirconium phosphate; Laminar materials; Supramolecular chirality; Circularly polarized luminescence; Lanthanide luminescence; POLYMER; AMPLIFICATION; COORDINATION; PHOSPHATE; INVERSION; CHIRALITY; EU(III); FILMS;
D O I：
10.1016/j.micromeso.2012.11.009
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Solid-state CPL measurements were performed for the first time on hybrid, laminar materials based on gamma-ZrP pillared with organic diphosphonates. Ad hoc optically pure diphosphonates were synthesized and the luminescence properties of their complexation with Tb(III) were verified in solution. CD and CPL measurements showed that the bistriazolylpyridine chromophores bonded to the metal provided an effective chiral environment that produced significant signals. In the case of the gamma-ZrP-derived materials, experimental evidence and simple molecular modeling hinted to the occurrence of supramolecular chirality in the particles, induced by the intrinsic dissymmetry of the organic diphosphonates or by the intercalation of chiral species such as 1-phenethylamine. Chirality at the supramolecular level was revealed in the solid state by the CPL signals measured from reporter Tb(III) ions intercalated in the hybrid matrix. (C) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码：222 / 234
页数：13
相关论文
共 31 条
[1]   Optical isomers of N,N′-bis(1-phenylethyl)-2,6-pyridinedicarboxamide coordinated to europium(III) ions as reliable circularly polarized luminescence calibration standards [J].
Bonsall, Steven D. ;
Houcheime, Mona ;
Straus, Daniel A. ;
Muller, Gilles .
CHEMICAL COMMUNICATIONS, 2007, (35) :3676-3678
[2]   Solid-state reshaping of nanostructured crystals:: supramolecular chirality of layered materials derived from polyethylenoxa-pillared zirconium phosphate [J].
Brunet, E ;
de la Mata, MJ ;
Juanes, O ;
Alhendawi, HMH ;
Cerro, C ;
Rodríguez-Ubis, JC .
TETRAHEDRON-ASYMMETRY, 2006, 17 (03) :347-354
[3]   Engineering of microcrystaline solid-state networks using cross-linked γ-zirconium phosphate/hypophosphite with nonrigid polyethylenoxadiphosphonates.: Easy access to porously dynamic solids with polar/nonpolar pores [J].
Brunet, E ;
de la Mata, MJ ;
Alhendawi, HMH ;
Cerro, C ;
Alonso, M ;
Juanes, O ;
Rodríguez-Ubis, JC .
CHEMISTRY OF MATERIALS, 2005, 17 (06) :1424-1433
[4]   Sensitized luminescence of lanthanides within the walls of polyethylenoxa-pillared γ-zirconium phosphate [J].
Brunet, E ;
de la Mata, MJ ;
Juanes, O ;
Rodríguez-Ubis, JC .
CHEMISTRY OF MATERIALS, 2004, 16 (08) :1517-1522
[5]  
Brunet E, 2009, J MEX CHEM SOC, V53, P155
[6]   Click-chemistry-based bis-triazolylpyridine diphosphonate ligand for the sensitized luminescence of lanthanides in the solid state within the layers of γ-zirconium phosphate [J].
Brunet, Ernesto ;
Juanes, Olga ;
Jimenez, Laura ;
Carlos Rodriguez-Ubis, Juan .
TETRAHEDRON LETTERS, 2009, 50 (38) :5361-5363
[7]   Luminescence of lanthanides in covalently pillared zirconium phosphate [J].
Brunet, Ernesto ;
Alhendawi, Hussein M. H. ;
Juanes, Olga ;
Jimenez, Laura ;
Carlos Rodriguez-Ubis, Juan .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (17) :2494-2502
[8]  
Chen HP, 2000, ADV MATER, V12, P1283, DOI 10.1002/1521-4095(200009)12:17<1283::AID-ADMA1283>3.0.CO
[9]  
2-P
[10]   Circularly polarized light generated by photoexcitation of luminophores in glassy liquid-crystal films [J].
Chen, SH ;
Katsis, D ;
Schmid, AW ;
Mastrangelo, JC ;
Tsutsui, T ;
Blanton, TN .
NATURE, 1999, 397 (6719) :506-508
1234