Carborane Photochemistry Triggered by Aryl Substitution: Carborane-Based Dyads with Phenyl Carbazoles

被引：216
作者：
Wee, Kyung-Ryang [1 ]
Han, Won-Sik [1 ]
Cho, Dae Won [1 ]
Kwon, Soonnam [1 ]
Pac, Chyongjin [1 ]
Kang, Sang Ook [1 ]
机构：
[1] Korea Univ, Dept Chem Mat, Chungnam 339700, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 11期
基金：
新加坡国家研究基金会;
关键词：
boranes; cage compounds; electron transfer; photophysics; AGGREGATION-INDUCED EMISSION; O-CARBORANE; POLY(N-VINYLCARBAZOLE); COMPLEXES; ANIONS;
D O I：
10.1002/anie.201109069
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bright combination: A new type of donor-acceptor dyad, carbazolylaryl-substituted ortho-carboranes, which are conveniently prepared from the corresponding acetylenes and decaborane pathways, showed unique excited-state behavior associated with electron transfer unlike the meta- and para-counterparts (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2677 / 2680
页数：4
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