Nanoscale Block Copolymer Ordering Induced by Visible Interferometric Micropatterning: A Route towards Large Scale Block Copolymer 2D Crystals

被引：39

作者：

Aissou, Karim ^{[1
]}

Shaver, Jonah ^{[2
]}

Fleury, Guillaume ^{[1
]}

Pecastaings, Gilles ^{[1
]}

Brochon, Cyril ^{[1
]}

Navarro, Christophe ^{[3
]}

Grauby, Stephane ^{[2
]}

Rampnoux, Jean-Michel ^{[2
]}

Dilhaire, Stefan ^{[2
]}

Hadziioannou, Georges ^{[1
]}

机构：

[1] Univ Bordeaux, Lab Chim Polymeres Organ, CNRS, LCPO,UMR 5629, F-33600 Pessac, France

[2] Univ Bordeaux, Lab Ondes & Mat Aquitaine, CNRS, LOMA,UMR 5798, F-33400 Talence, France

[3] ARKEMA, Groupement Rech Lacq, RN 117, F-64170 Lacq, France

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 02期

关键词：

block copolymers; surface relief grating; thin films; corrugated substrates; microstructures; micropatterning; 2D crystals; DIBLOCK COPOLYMER; THIN-FILMS; FEPT NANOPARTICLES; SYSTEM; LITHOGRAPHY; SURFACES; DOMAINS; ARRAYS;

D O I：

10.1002/adma.201203254

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have overcome the cost and time consumption limitations of common lithography techniques used to control the self-assembly of block copolymers into highly ordered 2D arrays through the use of a guiding pattern created from a polymeric sub-layer. The guiding pattern is a sinusoidal surface-relief grating interferometrically inscribed onto an azobenzene containing copolymer sub-layer leading to a defect-free single grain of block copolymer domains. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：213 / 217

页数：5

共 9 条

[1] Large-Area 2D Gold Nanorod Arrays Assembled on Block Copolymer Templates
Liu, Zhicheng
Huang, Haiying
He, Tianbai
SMALL, 2013, 9 (04) : 505 - 510
[2] Controlled Assembly of Block Copolymer Coated Nanoparticles in 2D Arrays
Leffler, Vanessa B.
Mayr, Lina
Paciok, Paul
Du, Hongchu
Dunin-Borkowski, Rafal E.
Dulle, Martin
Foerster, Stephan
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (25) : 8541 - 8545
[3] Fabrication of 2D photonic crystals using block copolymer patterns on as grown LEDs
Alam, Md Mahbub
Kim, Jin-Yeol
Jung, Woo-Gwang
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 363 (02) : 446 - 449
[4] Phase transition of block copolymer/homopolymer binary blends under 2D confinement
Kim, Youngkeol
Mun, Jaewan
Yu, Guiduk
Char, Kookheon
MACROMOLECULAR RESEARCH, 2017, 25 (06) : 656 - 661
[5] Interfacial self-assembly of amphiphilic conjugated block copolymer into 2D nanotapes
Guo, Xiao-Shuai
Zhang, Ze-Kun
Zhang, Tian-Yu
Tong, Zai-Zai
Xu, Jun-Ting
Fan, Zhi-Qiang
SOFT MATTER, 2019, 15 (43) : 8790 - 8799
[6] Phase transition of block copolymer/homopolymer binary blends under 2D confinement
Youngkeol Kim
Jaewan Mun
Guiduk Yu
Kookheon Char
Macromolecular Research, 2017, 25 : 656 - 661
[7] Reversible 2D/3D Coatings from Zipper-Assembly of Block Copolymer Micelles
Tyagi, Prashant
Raschip, Irina Elena
Deratani, Andre
Quemener, Damien
ADVANCED MATERIALS, 2013, 25 (27) : 3739 - 3744
[8] Bridging the Gap between the Mesoscopic 2D Order-Order Transition and Molecular-Level Reorganization in Dot-Patterned Block Copolymer Monolayers
Richard-Lacroix, Marie
Borozenko, Kateryna
Pellerin, Christian
Bazuin, C. Geraldine
MACROMOLECULES, 2016, 49 (23) : 9089 - 9099
[9] Magnetic Field-Induced Order-Order Transition from Hexagonally Packed Cylinders to Lamellae with Large-Scale Orientations in a Block Copolymer/Magnetic Nanoparticle Nanocomposite Film
Ren, Bo H.
Chu, Che Y.
Jhang, Bo S.
MACROMOLECULES, 2023, 56 (09) : 3363 - 3373

← 1 →