Crystallization of chiral compounds: thermodynamical, structural and practical aspects

被引：43
作者：
Bredikhin, Alexander A. [1 ]
Bredikhina, Zemfira A. [1 ]
Zakharychev, Dmitry V. [1 ]
机构：
[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
来源：
MENDELEEV COMMUNICATIONS | 2012年 / 22卷 / 04期
关键词：
CRYSTAL-STRUCTURE PREDICTION; SOLID-STATE PROPERTIES; SUPRAMOLECULAR SYNTHON APPROACH; SPONTANEOUS RESOLUTION; PREFERENTIAL CRYSTALLIZATION; ABSOLUTE-CONFIGURATION; GLYCEROL DERIVATIVES; OPTICAL ISOMERS; PROPRANOLOL HYDROCHLORIDE; ASYMMETRIC EPOXIDATION;
D O I：
10.1016/j.mencom.2012.06.001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Within a single family of aryl glycerol ethers and their simplest derivatives, examples of all known types of chiral crystallization, viz., conglomerates, racemic compounds, anomalous racemates and ideal and nonideal solid solutions have been found. A relationship was demonstrated between the crystal packing organization and chirality driven properties of organic substances, such as supramolecular gelation, capacity for enantiomeric enrichment and spontaneous resolution.
引用
收藏
页码：171 / 180
页数：10
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