Role of Al in Zn bath on the formation of the inhibition layer during hot-dip galvanizing for a 1.2Si-1.5Mn transformation-induced plasticity steel

被引：24
作者：
Wang, Kuang-Kuo [1 ]
Hsu, Chiung-Wen [1 ]
Chang, Liuwen [1 ]
Gan, Dershin [1 ]
Yang, Kuo-Cheng [2 ]
机构：
[1] Natl Sun Yat Sen Univ, Dept Mat & Optoelect Sci, Res Ctr Phys Properties & Microstruct Met, Kaohsiung 80424, Taiwan
[2] China Steel Corp, Steel Res & Dev Dept, Kaohsiung 81233, Taiwan
来源：
APPLIED SURFACE SCIENCE | 2013年 / 285卷
关键词：
Steel; Zinc; TEM; XPS; Selective oxidation; Interfaces; SELECTIVE OXIDATION; DEW-POINT; TRIP; SI; OXIDES; ATMOSPHERE; MORPHOLOGY; INTERFACE; BEHAVIOR; KINETICS;
D O I：
10.1016/j.apsusc.2013.08.077
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This study investigated the interaction between the Al in the Zn bath and the surface oxides formed by selective oxidation on a 1.2Si-1.5Mn TRIP steel during hot-dip galvanizing. XPS and TEM were employed for characterization. The results indicated that the amorphous xMnO center dot SiO2 oxide could react with Al to form a Si-Mn-Al-containing oxide. The crystalline MnSiO3 and Mn2SiO4 oxides could be largely reduced by Al to form holes in the oxide film. Consequently, the steel covered by a layer of mixed xMnO center dot SiO2 and MnSiO3 could form a continuous Fe2Al5 inhibition layer and showed the highest galvanizability among the three samples examined. (C) 2013 Elsevier B.V. All rights reserved.
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收藏
页码：458 / 468
页数：11
相关论文
共 40 条
[1]   Studies of the morphology of the Al-Rich interfacial layer formed during the hot dip galvanizing of steel sheet [J].
Baril, E ;
Lespérance, G .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1999, 30 (03) :681-695
[2]   Analysis of the Fe-Zn interface of galvanized high Al-low Si TRIP steels [J].
Bellhouse, E. M. ;
McDermid, J. R. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 491 (1-2) :39-46
[3]   Selective Oxidation and Reactive Wetting During Hot-Dip Galvanizing of a 1.0 pct Al-0.5 pct Si TRIP-Assisted Steel [J].
Bellhouse, E. M. ;
McDermid, J. R. .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2012, 43A (07) :2426-2441
[4]   Selective Oxidation and Reactive Wetting during Galvanizing of a CMnAl TRIP-Assisted Steel [J].
Bellhouse, E. M. ;
McDermid, J. R. .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2011, 42A (09) :2753-2768
[5]   Selective Oxidation and Reactive Wetting of 1.0 Pct Si-0.5 Pct Al and 1.5 Pct Si TRIP-Assisted Steels [J].
Bellhouse, E. M. ;
McDermid, J. R. .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2010, 41A (06) :1539-1553
[6]   Hydrodynamic effects an galvanising of high strength steels [J].
Bordignon, L .
ISIJ INTERNATIONAL, 2001, 41 (02) :168-174
[7]   Morphology and kinetics of interfacial layer formation during continuous hot-dip galvanizing and galvannealing [J].
Chen, L. ;
Fourmentin, R. ;
Mc Dermid, J. R. .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2008, 39A (09) :2128-2142
[8]   Influence of Gas Atmosphere Dew Point on the Selective Oxidation and the Reactive Wetting During Hot Dip Galvanizing of CMnSi TRIP Steel [J].
Cho, Lawrence ;
Lee, Seok Jae ;
Kim, Myung Soo ;
Kim, Young Ha ;
De Cooman, Bruno C. .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2013, 44A (01) :362-371
[9]  
De Meyer M, 1999, ISIJ INT, V39, P813
[10]  
Drillet P., 2004, Galvatech'04 Conference Proceedings, P1123, DOI DOI 10.1051/METAL:2004154
1234