Highly Sensitive, Uniform, and Reproducible SurfaceEnhanced Raman Spectroscopy from Hollow Au-Ag Alloy Nanourchins

被引:263
作者
Liu, Zhen [1 ]
Yang, Zhongbo [1 ]
Peng, Bo [2 ]
Cao, Cuong [2 ]
Zhang, Chao [3 ]
You, Hongjun [1 ]
Xiong, Qihua [2 ]
Li, Zhiyuan [3 ]
Fang, Jixiang [1 ]
机构
[1] Xi An Jiao Tong Univ, Sch Sci, State Key Lab Mech Behav Mat, Xian 710049, Shann Xi, Peoples R China
[2] Nanyang Technol Univ, Sch Phys & Math Sci, Div Phys & Appl Phys, Singapore 637371, Singapore
[3] Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
基金
新加坡国家研究基金会; 中国国家自然科学基金;
关键词
surface-enhanced Raman spectroscopy; nanourchins; hollow Au-Ag alloy; sensitivity; reproducibility; SILVER NANOPARTICLES; SCATTERING; ARRAYS; FABRICATION; ASSEMBLIES; CHLORIDE; CRYSTAL; DIMERS;
D O I
10.1002/adma.201305106
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hierarchical nanoparticle strategy to simultaneously gain super Raman signal amplification, high uniformity, and reproducibility is presented. Using hollow Au-Ag alloy nanourchins, an ultrahigh sensitivity, e.g., down to 1 fM concentrations for DEHP molecule is obtained. A small standard deviation of <10% is achieved by simply dropping and evaporating sub-100 nm nanourchins onto a substrate. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2431 / 2439
页数:9
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