Unprecedented helix-based microporous metal-organic frameworks constructed from a single ligand

被引：35
作者：
Sang, Rui-Li [1 ,2 ]
Xu, Li [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 46期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1039/b814524e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unprecedented helix-based MMOFs with a cylindrical channel constructed from a single, newly designed Na(2)Pra(2)biim [Na(2)Pra(2)biim = 1,1'-di(propionic acid)-2,2'-biimidazole disodium salt], [M(Pra(2)biim)(H2O)](n)center dot xnH(2)O (M = Cd, Pb) have been presented, which are built from alternately arranged left- and right-handed helical M-biim tubes interconnected by the carboxyl arms of the ligand, and these findings reveal the promising potential of functionalized helical ligands in the construction of helix-based MMOFs from a single linker.
引用
收藏
页码：6143 / 6145
页数：3
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