Oxidation of five-member heteroaldehydes by quinolinium dichromate. A kinetic study

被引：0
|
作者：
Chaubey, GS [1 ]
Mahanti, MK [1 ]
机构：
[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India
来源：
OXIDATION COMMUNICATIONS | 2006年 / 29卷 / 01期
关键词：
kinetics; oxidation; heterocyclic aldehydes; quinolinium dichromate;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Quinolinium dichromate in sulphuric acid oxidised five-member heterocyclic aldehydes to the corresponding acids in 50% (v/v) acetic acid-water medium. The kinetic results supported a mechanistic pathway proceeding via a rate-determining decomposition of the chromate ester.
引用
收藏
页码：86 / 94
页数：9
相关论文
共 50 条
  • [31] Kinetic features of the quinolinium dichromate oxidation of long-chain secondary alcohols
    Nongkynrih, I.
    Mahanti, M. K.
    OXIDATION COMMUNICATIONS, 2007, 30 (03): : 593 - 600
  • [32] A DFT study on the mechanism of Wolff Rearrangement in a five-member Iridacycle
    Fan, Yubo
    Bacon, Stephen
    Kolade, Akindejoye
    Wasiu, Abiouye
    Fan, Hua-Jun
    ICCS 2010 - INTERNATIONAL CONFERENCE ON COMPUTATIONAL SCIENCE, PROCEEDINGS, 2010, 1 (01): : 2653 - 2661
  • [33] A comparative study of quinolinium dichromate oxidation with hydrophobic dependence amino acids. A kinetic and mechanistic approach
    Ravishankar, Sukanya L.
    Baba, Ramesha A.
    Gowda, Rangaswamy
    Gowda, Channe D.
    TRANSITION METAL CHEMISTRY, 2007, 32 (03) : 407 - 410
  • [34] A comparative study of quinolinium dichromate oxidation with hydrophobic dependence amino acids. A kinetic and mechanistic approach
    Sukanya L. Ravishankar
    Ramesha A. Baba
    Channe D. Rangaswamy
    Transition Metal Chemistry, 2007, 32 : 407 - 410
  • [35] Kinetic features of the carbon-carbon bond cleavage in the oxidation of diketones by quinolinium dichromate
    Das, S.
    Mahanti, M. K.
    OXIDATION COMMUNICATIONS, 2007, 30 (02): : 405 - 410
  • [36] Oxidation of Graphene-Edge Six- and Five-Member Rings by Molecular Oxygen
    Singh, Ravi I.
    Mebel, Alexander M.
    Frenklach, Michael
    JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (28): : 7528 - 7547
  • [37] Peroxydase catalysed oxidation of alcohols and aliphatic amines by quinolinium dichromate in aqueous buffer and micellar media : A kinetic study.
    Rajanna, KC
    Humaira, T
    Kumar, UU
    Sundari, LBT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U394 - U394
  • [38] Ab initio study of potential energy surface of five-member rings.
    Feng, J
    Lambert, MH
    Young, SS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U491 - U492
  • [39] Oxidation of Isoniazid by Quinolinium Dichromate in an Aqueous Acid Medium and Kinetic Determination of Isoniazid in Pure and Pharmaceutical Formulations
    Raviraj M. Kulkarni
    Dinesh C. Bilehal
    Sharanappa T. Nandibewoor
    Analytical Sciences, 2004, 20 : 743 - 747
  • [40] Oxidation of crotonaldehyde by quinolinium chlorochromate (QCC). A kinetic study
    Mishra, K
    Singh, J
    Agrawal, GL
    Pandey, A
    OXIDATION COMMUNICATIONS, 2003, 26 (01): : 52 - 58
12345