ZnCl3(4-methyl-4,4′-bipyridinium) with 4-methyl-4,4′-bipyridinium generated in situ: synthesis, structure and photoluminescence

被引：20
作者：
Chen, Wen-Tong [1 ]
Liu, Dong-Sheng [1 ]
Ying, Shao-Ming [1 ]
Chen, Hua-Long [1 ]
Xu, Ya-Ping [1 ]
机构：
[1] Jinggangshan Univ, Sch Chem & Chem Engn, Jiangxi Prov Key Lab Coordinat Chem, Jian 1343009, Jiangxi, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 10期
关键词：
Bipyridine; In situ; Photoluminescence; Viologen; Zinc;
D O I：
10.1016/j.inoche.2008.07.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel viologen(4,4'-bipyridinium)-based complex ZnCl3(4-methyl-4,4'-bipyridinium) (1), in which the 4-methyl-4,4'-bipyridinium (MQ(+)) was generated in situ, has been synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The title complex features an isolated structure, based on the MQ(+) ligand coordinating to a zinc atom that is further terminally bound by three chlorine atoms. Photoluminescence investigation reveals a strong emission in blue region, which may originate from pi ->pi charge-transfer interaction of the MQ(+) ligand. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1212 / 1214
页数：3
相关论文
共 25 条
[1]   Oxo-centered mixed-ligand triruthenium complexes having redox-active N-methyl-4,4'-bipyridinium ions (mbpy(+)). Reversible multistep electrochemical properties of [RuIII2RuII(mu(3)-O)(mu-CH3CO2)(6)(mbpy(+))(2)(CO)](2+) and [RuIII3(mu(3)-O)(mu-CH3CO2)(6)(mbpy(+))(2)(L)](3+) (L=H2O and n-heterocyclic ligands) [J].
Abe, M ;
Sasaki, Y ;
Yamada, Y ;
Tsukahara, K ;
Yano, S ;
Yamaguchi, T ;
Tominaga, M ;
Taniguchi, I ;
Ito, T .
INORGANIC CHEMISTRY, 1996, 35 (23) :6724-6734
[2]   Comment on "On the presence of multiple molecules in the crystal asymmetric unit (Z′ > 1)'' by Gautam R.!Desiraju, CrystEngComm, 2007, 9, 91 [J].
Anderson, Kirsty M. ;
Steed, Jonathan W. .
CRYSTENGCOMM, 2007, 9 (04) :328-330
[3]   Structural consequences of M-Cl center dot center dot center dot H-N hydrogen bonds in substituted pyridinium salts of the cobalt(II)tetrachloride anion isolated from liquid clathrate media [J].
Barbour, LJ ;
MacGillivray, LR ;
Atwood, JL .
SUPRAMOLECULAR CHEMISTRY, 1996, 7 (02) :167-169
[4]   Discrete dinuclear and polymeric copper(I) cations bridged by 4,4'-bipyridine, trans-1,2-bis(4-pyridyl)ethene or bis(4-pyridyl) disulfide [J].
Batsanov, AS ;
Begley, MJ ;
Hubberstey, P ;
Stroud, J .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (09) :1947-1957
[5]   In situ formation of heterobimetallic salen complexes containing titanium and/or vanadium ions [J].
Belokon, Yuri N. ;
Clegg, William ;
Harrington, Ross W. ;
North, Michael ;
Young, Carl .
INORGANIC CHEMISTRY, 2008, 47 (09) :3801-3814
[6]   Metal-assisted in situ formation of a tridentate acetylacetone ligand for complexation of fac-Re(CO)3+ for radiopharmaceutical applications [J].
Benny, Paul D. ;
Fugate, Glenn A. ;
Barden, Adam O. ;
Morley, Jennifer E. ;
Silva-Lopez, Elsa ;
Twamley, Brendan .
INORGANIC CHEMISTRY, 2008, 47 (07) :2240-2242
[7]   Photochemical and thermal synthesis and characterization of polypyridine ruthenium(II) complexes containing different monodentate ligands [J].
Bonnet, S ;
Collin, JP ;
Gruber, N ;
Sauvage, JP ;
Schofield, ER .
DALTON TRANSACTIONS, 2003, (24) :4654-4662
[8]   Synthesis, structure, and photoelectronic effects of a uranium-zinc-organic coordination polymer containing infinite metal oxide sheets [J].
Chen, W ;
Yuan, HM ;
Wang, JY ;
Liu, ZY ;
Xu, JJ ;
Yang, M ;
Chen, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (31) :9266-9267
[9]   μ-(4,4'-Bipyridine)-N:N'-bis[bis(pyrrolidinedithiocarboxylato-S,S') zinc(II)] [J].
Chen, XF ;
Liu, SH ;
Zhu, XH ;
Vittal, JJ ;
Tan, GK ;
You, XZ .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 :42-43
[10]   Solvothermal in situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry [J].
Chen, Xiao-Ming ;
Tong, Ming-Liang .
ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (02) :162-170
123