μ-Hexatriacontaoxophosphatododecamolybdatobis[bis(1,10-phenanthroline)copper(II)]

被引：0
|
作者：
Bai, YP [1 ]
Wang, E [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxomet Chem, Changchun 130024, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806002832
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu2Mo12O40P(C12H8N2)(4)], was obtained by the hydrothermal reaction of Na2MoO4 center dot 2H(2)O, Cu(CH3-COO)(2)center dot H2O, NH4VO3, 1,10-phenanthroline (phen) and H3PO4. The structure determination shows that two {Cu(phen)(2)} fragments are supported by the reduced alpha-Keggin polyoxoanion [(PMo11MoO40)-Mo-VI-O-V](4-) through a terminal O atom and a bridging oxygen atom from opposite sides of the Keggin structure.
引用
收藏
页码：M526 / M528
页数：3
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