Sulfur-doped microporous carbons developed from coal for enhanced capacitive performances of supercapacitor electrodes

被引:24
作者
Feng, Yanyan [1 ]
Huang, Hongbin [1 ]
Yang, Wen [1 ]
Huang, Wenlu [1 ]
Xia, Yilang [1 ]
Yi, Yajun [1 ]
Zhang, Xinju [1 ]
Zhang, Shufen [1 ,2 ]
机构
[1] Guilin Univ Technol, Dept Chem & Bioengn, Guangxi Key Lab Electrochem & Magnetochem Funct M, Guilin, Peoples R China
[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian, Peoples R China
基金
中国国家自然科学基金;
关键词
Supercapacitor electrode; microporous carbons; sulfur-doping; cycle stability; BIOMOLECULE-ASSISTED SYNTHESIS; ADSORPTION BEHAVIORS; MESOPOROUS CARBON; ACTIVATED CARBONS; NITROGEN; METHANE; SURFACE; SULFIDE;
D O I
10.1080/10584587.2018.1454763
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Sulfur-doped microporous carbons have been fabricated through a facile pyrolyzing method using the raw coal as the carbon precursor and K2S as porogen and the sulfur source. Benefiting from the characteristics of appropriate BET surface area, abundant microporous structure and sulfur functionality, the sample Coal-K2S-750 exhibited a high specific capacitance of 188.9F/g at 0.5A/g and 123.0F/g at 10A/g as well as the excellent cycling stability with the capacitance fading of 3.6% over 5000 cycles at 5.0A/g.
引用
收藏
页码:44 / 56
页数:13
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