Synthesis and crystal structure of a novel zincophosphite containing two-dimensional inorganic-organic network

被引：0
作者：
Yang, YL [1 ]
Li, N [1 ]
Xiang, SH [1 ]
机构：
[1] Nankai Univ, Coll Chem, Inst New Catalyt Mat Sci, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2004年 / 22卷 / 04期
关键词：
zincophosphite; hydrothermal synthesis; two-dimensional; network;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel 1,6-hexamethylenediamine-zincophosphite has been synthesized hydrothermally. Its single-crystal structure refinement has shown the zincophosphite with the composition NH3+ (CH2)(6) NH3+ [Zn(HPO3)(2)](2-), M-r = 343.55. It crystallizes in monoclinic, space group C2/c (No.15), a=2.2391 nm, b=0.8695 nm, c=0.7919 nm, beta = 101.062(6)degrees, V= 1.513 nm(3), D-c=1.508 kg/m(3), Z=4, F(000)=712,mu= 1.849 mm(-1), R-1=0.0416, wR(2)=0.1023. This phase exhibits infinite inorganic chains of vertex-linked ZnO4 and HPO3. Via the electrostatic attraction, 1,6-hexainethylenediamine cations and inorganic chains construct a novel interesting two-dimensional inorganic-organic network.
引用
收藏
页码：344 / 347
页数：4
相关论文
共 18 条
  • [1] [Anonymous], 2015, Acta Crystallogr., V71, P3
  • [2] BECKER G, 1990, Z ANORG ALLG CHEM, V17, P591
  • [3] Breck D.W, 1974, ZEOLITE MOL SIEVES
  • [4] *BRUK AXS INC, 1999, BRUK SOFTW CCD DIFF
  • [5] Tetrahedral-network organo-zincophosphates:: Syntheses and structures of (N2C6H14)•Zn(HPO4)2•H2O, H3N(CH2)3NH3•Zn2(HPO4)3, and (N2C6H14)•Zn3(HPO4)4
    Chavez, AV
    Nenoff, TM
    Hannooman, L
    Harrison, WTA
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1999, 147 (02) : 584 - 591
  • [6] Open-framework zinc phosphates synthesized in the presence of structure-directing organic amines
    Chidambaram, D
    Neeraj, S
    Natarajan, S
    Rao, CNR
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1999, 147 (01) : 154 - 169
  • [7] (CN4H7)2•Zn3(HPO3)4, a three-dimensional framework zincophosphite:: an example of template-template co-operation?
    Harrison, WTA
    Phillips, MLF
    Nenoff, TM
    [J]. INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2001, 3 (07): : 1033 - 1038
  • [8] (CN3H6)2•Zn(HPO3)2:: An open-framework zincophosphite built up from polyhedral 12-rings
    Harrison, WTA
    Phillips, MLF
    Nenoff, TM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (17): : 2459 - 2461
  • [9] H3N(CH2)3NH3•Zn(HPO3)2 containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids
    Harrison, WTA
    [J]. INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2001, 3 (02): : 187 - 189
  • [10] Pseudopyramidal building units in mixed inorganic/organic network solids:: Syntheses, structures, and properties of α- and β-ZnHPO3•N4C2H4
    Harrison, WTA
    Phillips, MLF
    Stanchfield, J
    Nenofff, TM
    [J]. INORGANIC CHEMISTRY, 2001, 40 (05) : 895 - 899
12