An unprecedented (3,4)-connected self-penetrating metal-organic framework

被引：6
|
作者：
Hua, Rong [1 ,2 ]
Wu, Xiao Liu [2 ]
Li, Jin Ying [1 ]
Shi, Lei [1 ]
Luo, Feng [2 ]
机构：
[1] China Inst Atom Energy, Beijing 102413, Peoples R China
[2] E China Inst Technol, Coll Biol Chem & Mat Sci, Nanchang 330013, Jiangxi, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 39卷
关键词：
MOFs; Solvo(hydro)thermal method; (3,4)-connected; Self-penetrating; LIGAND;
D O I：
10.1016/j.inoche.2013.10.034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this work, we obtained a highly rare three-dimensional Zn(II) MOF, namely [Zn-2(BTC)(2)(L)][(Me2NH2)(2)].DMF (BTC3- = 1,3,5-benzenetricarboxylate, L = N-1,N-4-bis(pyridin-3-ylmethyl)cyclohexane-1,4-dicarboxamide), and Me2NH2 = dimethylamine cation) by solvo(hydro)thermal method. This polymer was characterized by single-crystal X-ray diffraction, thermogravimetry and solid-state luminescence analysis. The outstanding structural feature of it is (3, 4)-connected net with unprecedented (6 . 8(2))(6 . 8(5))(6(2) . 10)(6(2) . 8(3) . 10) topology and self-penetrating motif. (C) 2013 Published by Elsevier B.V.
引用
收藏
页码：90 / 93
页数：4
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