POSS-based luminescent hybrid material for enhanced photo-emitting properties

被引：10
|
作者：
Kumar, B. Prem [1 ]
Vijaykumar, B. V. D. [1 ]
Raghavan, C. M. [2 ]
Harshavardhan, S. J. [1 ]
Yi, Soung-Soo [3 ]
Gandhi, Sakthivel [2 ]
Jiang, Jianzhuang [4 ]
Jang, Kiwan [2 ]
Shin, Dong-Soo [1 ]
机构：
[1] Changwon Natl Univ, Dept Chem, Gyeongsangnam Do 641773, Changwon, South Korea
[2] Changwon Natl Univ, Dept Phys, Gyeongsangnam Do 641773, Changwon, South Korea
[3] Silla Univ, Dept Elect Mat Engn, Pusan 617736, South Korea
[4] Univ Sci & Technol Beijing, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China
来源：
JOURNAL OF MATERIALS SCIENCE | 2013年 / 48卷 / 21期
基金：
新加坡国家研究基金会;
关键词：
POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; COMPLEXES; POLYMERS; LIQUID; CORES; CHEMISTRY; DESIGN; IONS;
D O I：
10.1007/s10853-013-7568-2
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this present work, we have developed a novel POSS type monomer ligand "2,6-pyridinediamine-bis-(propanylheptaisobutyl POSS)" (PDC-POSS) and utilized in the preparation of potential luminescent hybrid complex Eu-PDC-POSS with an inner transition metal ion Eu3+. The solubility and photo-emitting properties of new Eu-PDC-POSS hybrid material were studied. The precursor PDC-POSS was synthesized by treating (3-aminopropyl)heptaisobutyl POSS with PDC (2,6-pyridinedicarboxylic acid chloride), and then coordinated with Eu3+ using europium nitrate to afford Eu-PDC-POSS hybrid material. The europium-doped hybrid material was characterized using fourier transform infrared spectroscopy, and scanning electron microscopy along with energy dispersive X-ray analysis. The photo emitting properties were studied using a fluorescence spectrophotometer in which, the results showed enhancement in red emission peak at 618 nm for Eu-PDC-POSS, when compared to that of a known solgel-based material Eu-PDC-solgel.
引用
收藏
页码：7533 / 7539
页数：7
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