Polyene cyclization promoted by the cross conjugated alpha-carbalkoxy enone system. Application to the total synthesis of (+/-)-dehydrochamaecynenol

被引：15
作者：
Liu, HJ
Sun, DQ
机构：
[1] Department of Chemistry, University of Alberta, Edmonton
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 35期
基金：
加拿大自然科学与工程研究理事会;
关键词：
D O I：
10.1016/S0040-4039(97)01424-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The title cyclization process has been effectively applied to the first total synthesis of dehydrochamaecynenol in racemic form. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：6159 / 6162
页数：4
相关论文
共 12 条
[1]  
ASAO T, 1968, TETRAHEDRON LETT, P3639
[2]  
COREY EJ, 1972, TETRAHEDRON LETT, P3769
[3]   TOTAL SYNTHESIS OF DL-SIRENIN [J].
COREY, EJ ;
ACHIWA, K ;
KATZENEL.JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (15) :4318-&
[4]   CONVERSION OF ANDROSTENOLONE TO PREGNENOLONE [J].
DANISHEFSKY, S ;
NAGASAWA, K ;
WANG, N .
JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (13) :1989-1990
[5]  
GANEM B, 1974, TETRAHEDRON LETT, P917
[6]  
KENDE AS, 1985, ORG SYNTH, V64, P68
[7]   Polyene cyclization promoted by the cross conjugated alpha-carbalkoxy enone system [J].
Liu, HJ ;
Sun, DQ ;
Shia, KS .
TETRAHEDRON LETTERS, 1996, 37 (45) :8073-8076
[8]  
LIU HJ, 1995, SYNLETT, P545
[9]  
LIU HJ, IN PRESS CAN J CHEM
[10]   A CONVENIENT SYNTHESIS OF 1-BROMOOLEFINS AND ACETYLENES BY A CHAIN EXTENSION OF ALDEHYDES [J].
MATSUMOTO, M ;
KURODA, K .
TETRAHEDRON LETTERS, 1980, 21 (41) :4021-4024
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