Fabrication and Characterization of SiO2/(3-Aminopropyl)triethoxysilane-Coated Magnetite Nanoparticles for Lead(II) Removal from Aqueous Solution

被引:111
作者
Mahdavi, Mahnaz [1 ,2 ]
Bin Ahmad, Mansor [1 ]
Haron, Md Jelas [3 ]
Gharayebi, Yadollah [4 ]
Shameli, Kamyar [1 ,5 ]
Nadi, Behzad [6 ]
机构
[1] Univ Putra Malaysia, Fac Sci, Dept Chem, Upm Serdang 43400, Selangor, Malaysia
[2] Islamic Azad Univ, Dept Polymer Engn, Shiraz, Iran
[3] Univ Putra Malaysia, Ctr Fdn Studies Agr Sci, Upm Serdang 43400, Selangor, Malaysia
[4] Islamic Azad Univ, Behbahan Branch, Dept Chem, Behbahan, Iran
[5] Mat & Energy Res Ctr, Karaj 3177983634, Iran
[6] UKM, Fac Engn & Built Environm, Bangi, Malaysia
关键词
Magnetic nano-adsorbent; Fe3O4/SiO2 composite nanoparticles; Adsorption; Amino-functionalization; EQUILIBRIUM ISOTHERM; FE3O4; NANOPARTICLES; HEAVY-METALS; ADSORPTION; KINETICS; PB(II); IONS;
D O I
10.1007/s10904-013-9820-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel nano-adsorbent SiO2/(3-aminopropyl)triethoxysilane-coated magnetite nanoparticles was synthesized for the adsorption of lead ions from water samples. Its structure and magnetic characteristics were characterized, by FTIR, powder X-ray diffraction, scanning electron microscope (SEM), transmission electron microscope (TEM) and vibrating sample magnetometry (VSM). Amino-functionalized SiO2 coated Fe3O4 magnetite nano-adsorbent exhibited superparamagnetic behavior and strong magnetization at room temperature. The efficiency of the nano-adsorbent in separation of the metals was evaluated by adsorption technique. Kinetic data were analyzed using the pseudo-first-order and pseudo-second-order equations. The data fitted very well to the pseudo-second-order kinetic model.The linear Langmuir and Freundlich models were applied to describe equilibrium isotherms and Langmuir model fitted well. The monolayer adsorption capacity was found as 17.65 mg/g at pH 4.0. Thermodynamic parameters such as free energy change (Delta GA degrees), enthalpy change (Delta HA degrees) and entropy change (Delta SA degrees) were also calculated. These parameters showed that the adsorption of Pb(II) onto nano-adsorbent was feasible, spontaneous and endothermic. The amino-functionalized SiO2 coated Fe3O4 magnetic nano-adsorbent shows high adsorption capability for metal ions from aqueous solutions via the chelation mechanisms. The Pb(II) loaded nano-adsorbent can be easily recovered from aqueous solution with magnetic separation and regenerated readily by acid treatment. The product of this work can be used as an effective and recyclable nano-adsorbent for the removal of metal ions in wastewater treatment.
引用
收藏
页码:599 / 607
页数:9
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