Molecular recognition properties of a charge-transfer host system composed of 10,10′-dihydroxy-9,9′-biphenanthryl and viologen derivatives

被引：16

作者：

Imai, Yoshitane ^{[1
]}

Kamon, Kensaku ^{[1
]}

Kido, Shingo ^{[1
]}

Sato, Tomohiro ^{[2
]}

Tajima, Nobuo ^{[3
]}

Kuroda, Reiko ^{[2
,4
]}

Matsubara, Yoshio ^{[1
]}

机构：

[1] Kinki Univ, Dept Appl Chem, Fac Sci & Engn, Osaka 5778502, Japan

[2] JST ERATO SORST Kuroda Chiromorphol Team, Meguro Ku, Tokyo 1530041, Japan

[3] Natl Inst Mat Sci, Principles Simulat Grp 1, Computat Mat Sci Ctr, Tsukuba, Ibaraki 3050047, Japan

[4] Univ Tokyo, Dept Life Sci, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 2008卷 / 28期

关键词：

charge-transfer complex; biphenanthryl; host-guest systems; molecular recognition; viologen;

D O I：

10.1002/ejoc.200800567

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A charge-transfer (CT) complex composed of racemic rac-10,10'-dihydroxy-9,9'-biphenanthryl as the electron-donor and the diquaternary derivative of 4,4'-bipyridinium (viologen) as the electron-acceptor has been formed by the inclusion of guest molecules. The color and diffuse reflectance spectra of this inclusion CT complex are sensitive to the guest molecules, and their properties can be tuned by changing the component viologen derivatives. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

引用

页码：4784 / 4789

页数：6

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