Copolymerization of Tris(methoxyethoxy)vinyl Silane with N-Vinyl Pyrrolidone: Synthesis, Characterization, and Reactivity Relationships

被引：10
|
作者：
Mohammed, Ameen Hadi [1 ,2 ]
Bin Ahmad, Mansor [1 ]
Shameli, Kamyar [3 ]
机构：
[1] Univ Putra Malaysia, Fac Sci, Dept Chem, Serdang 13100, Selangor, Malaysia
[2] Univ Baghdad, Coll Sci Women, Dept Chem, Baghdad 10071, Iraq
[3] Univ Teknol Malaysia, MJIIT, Kuala Lumpur 54100, Malaysia
来源：
INTERNATIONAL JOURNAL OF POLYMER SCIENCE | 2015年 / 2015卷
关键词：
METHYL-METHACRYLATE; STYRENE; VINYLPYRROLIDONE; ACRYLONITRILE; BEHAVIOR; RATIOS;
D O I：
10.1155/2015/219898
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Copolymer of tris(methoxyethoxy)vinyl silane (TMEVS) with N-vinyl pyrrolidone (NVP) was synthesized by free radical polymerization in dry benzene at 70 degrees C using benzoyl peroxide (BPO) as initiator. The copolymer was characterized by viscometer, FTIR, and H-1-NMR and its thermal properties were studied by DSC and TGA. The copolymer composition was determined by elemental analysis. The monomer reactivity ratios were calculated by linearization methods proposed by Fineman-Ross and Kelen-Tudos. The intersection method was proposed by Mayo-Lewis and nonlinear method was proposed by curve-fitting procedure. The microstructure of copolymer and sequence distribution of monomers in the copolymer were calculated by statistical method.
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页数：8
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