An improved Hummers method for eco-friendly synthesis of graphene oxide

被引：1849

作者：

Chen, Ji ^{[1
]}

Yao, Bowen ^{[1
]}

Li, Chun ^{[1
]}

Shi, Gaoquan ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

CARBON | 2013年 / 64卷

关键词：

GRAPHITE OXIDE; SHEETS; ACID;

D O I：

10.1016/j.carbon.2013.07.055

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An improved Hummers method without using NaNO3 can produce graphene oxide nearly the same to that prepared by conventional Hummers method. This modification does not decrease the yield of product, eliminating the evolution of NO2/N2O4 toxic gasses and simplifying the disposal of waste water because of the inexistence of Na+ and NO3- ions. For the first time, we also developed a prototype method of post-treating the waste water collected from the systems of synthesizing and purifying graphene oxide. The content of Mn2+ ions in the purified waste water was measured to be lower than the guideline value for drinking water. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：225 / 229

页数：5

共 30 条

[21] Graphene based new energy materials [J].

Sun, Yiqing ;

Wu, Qiong ;

Shi, Gaoquan .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (04) :1113-1132

[22] Oh, the Places You'll Go with Graphene [J].

Wassei, Jonathan K. ;

Kaner, Richard B. .

ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (10) :2244-2253

[23] Graphene: An Emerging Electronic Material [J].

Weiss, Nathan O. ;

Zhou, Hailong ;

Liao, Lei ;

Liu, Yuan ;

Jiang, Shan ;

Huang, Yu ;

Duan, Xiangfeng .

ADVANCED MATERIALS, 2012, 24 (43) :5782-5825

[24]

World Health Organization (WHO), 2011, MANG DRINK WAT BACKG

[25] Synthesis of high-quality graphene with a pre-determined number of layers [J].

Wu, Zhong-Shuai ;

Ren, Wencai ;

Gao, Libo ;

Liu, Bilu ;

Jiang, Chuanbin ;

Cheng, Hui-Ming .

CARBON, 2009, 47 (02) :493-499

[26] Highly conductive chemically converted graphene prepared from mildly oxidized graphene oxide [J].

Xu, Yuxi ;

Sheng, Kaixuan ;

Li, Chun ;

Shi, Gaoquan .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (20) :7376-7380

[27] Controlled synthesis of few-layered graphene sheets on a large scale using chemical exfoliation [J].

Zhang, Long ;

Li, Xuan ;

Huang, Yi ;

Ma, Yanfeng ;

Wan, Xiangjian ;

Chen, Yongsheng .

CARBON, 2010, 48 (08) :2367-2371

[28] Size-controlled synthesis of graphene oxide sheets on a large scale using chemical exfoliation [J].

Zhang, Long ;

Liang, Jiajie ;

Huang, Yi ;

Ma, Yanfeng ;

Wang, Yan ;

Chen, Yongsheng .

CARBON, 2009, 47 (14) :3365-3368

[29] Efficient Preparation of Large-Area Graphene Oxide Sheets for Transparent Conductive Films [J].

Zhao, Jinping ;

Pei, Songfeng ;

Ren, Wencai ;

Gao, Libo ;

Cheng, Hui-Ming .

ACS NANO, 2010, 4 (09) :5245-5252

[30] Graphene and Graphene Oxide: Synthesis, Properties, and Applications [J].

Zhu, Yanwu ;

Murali, Shanthi ;

Cai, Weiwei ;

Li, Xuesong ;

Suk, Ji Won ;

Potts, Jeffrey R. ;

Ruoff, Rodney S. .

ADVANCED MATERIALS, 2010, 22 (35) :3906-3924

← 1 2 3 →