Lead-free 0.7BiFeO3-0.3BaTiO3 high-temperature piezoelectric ceramics: Nano-BaTiO3 raw powder leading to a distinct reaction path and enhanced electrical properties

Herein, nano-BaTiO3/Bi2O3/Fe2O3 and BaCO3/TiO2/Bi2O3/Fe2O3 were respectively used to prepare 0.7BiFeO(3)-0.3BaTiO(3) (0.7BF-0.3BT) ceramics by conventional solid-state method and clarify the reaction path, phase structure, microstructure, ferroelectric, and piezoelectric properties. 0.7BF-0.3BT ceramic using nano-BaTiO3 with cubic phase (C-BT) undergoes the formation of rhombohedral alpha-phase (R-alpha) and the transition from R-alpha and C-BT to rhombohedral beta-phase (R-beta) and pseudo-cubic (PC) phases, while the counterpart using BaCO3/TiO2 directly generates R-beta and PC. Nano-BaTiO3 can decrease pores and oxygen vacancies in the resultant ceramics comparing to BaCO3/TiO2, which is due to an inhibited decomposition of R-alpha and a weaker reduction of Fe3+ to Fe2+, leading to increased density and reduced leakage current density. Benefitting from a proper phase ratio, increased density and reduced leakage current density, the enhanced piezoelectric properties d(33) = 210 pC/N, k(p) = 0.34, P-r = 31.2 mu C/cm(2) and T-C = 514 degrees C are obtained in 0.7BF-0.3BT ceramic using nano-BaTiO3. Our work reveals the importance of raw materials and the potential of BF-BT as a high-temperature lead-free piezoelectric ceramic material.